It depends on what you want to achieve. But ultimately doesn't matter.
Some standards recommend that both sides are isolated.
Is the objective an emergency off, that isolates everything in the event of smoke? Or is the objective short term storage (1-2 weeks) to minimise all parasitic loads on a single battery?
In a dual battery system, with solar, lithium BMS, voltage senses and all the extras you find hanging off the positive terminal and as close as possible to the battery I recommend a DPST on the negative side, that fully isolates both batteries in the event of smoke. T